We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AICC] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component. 相似文献
As well known, the methods of remote sensing and Bowen Ratio for retrieving surface flux are based on energy balance closure; however, in most cases, surface energy observed in experiment is lack of closure. There are two main causes for this: one is from the errors of the observation devices and the differences of their observational scale; the other lies in the effect of horizontal advection on the surface flux measurement. Therefore, it is very important to estimate the effects of horizontal advection quantitatively. Based on the local advection theory and the surface experiment, a model has been proposed for correcting the effect of horizontal advection on surface flux measurement, in which the relationship between the fetch of the measurement and pixel size for remote sensed data was considered. By means of numerical simulations, the sensitivities of the main parameters in the model and the scaling problems of horizontal advection were analyzed. At last, by using the observational data acquired in agricultural field with relatively homogeneous surface, the model was validated.
Long-term measurement of carbon metabolism of old-growth forests is critical to predict their behaviors and to reduce the uncertainties of carbon accounting under changing climate. Eddy covariance technology was applied to investigate the long-term carbon exchange over a 200 year-old Chinese broad-leaved Korean pine mixed forest in the Changbai Mountains (128°28′E and 42°24′N, Jilin Province, P. R. China) since August 2002. On the data obtained with open-path eddy covariance system and CO2 profile measurement system from Jan. 2003 to Dec. 2004, this paper reports (i) annual and seasonal variation of FNEE, FGPP and RE; (ii) regulation of environmental factors on phase and amplitude of ecosystem CO2 uptake and release Corrections due to storage and friction velocity were applied to the eddy carbon flux.
LAI and soil temperature determined the seasonal and annual dynamics of FGPP and RE separately. VPD and air temperature regulated ecosystem photosynthesis at finer scales in growing seasons. Water condition at the root zone exerted a significant influence on ecosystem maintenance carbon metabolism of this forest in winter.
The forest was a net sink of atmospheric CO2 and sequestered −449 g C·m−2 during the study period; −278 and −171 gC·m−2 for 2003 and 2004 respectively. FGPP and FRE over 2003 and 2004 were −1332, −1294 g C·m−2. and 1054, 1124 g C·m−2 respectively. This study shows that old-growth forest can be a strong net carbon sink of atmospheric CO2.
There was significant seasonal and annual variation in carbon metabolism. In winter, there was weak photosynthesis while the ecosystem emitted CO2. Carbon exchanges were active in spring and fall but contributed little to carbon sequestration on an annual scale. The summer is the most significant season as far as ecosystem carbon balance is concerned. The 90 days of summer contributed 66.9, 68.9% of FGPP, and 60.4, 62.1% of RE of the entire year.
Temperature front (TF) is one of the important features in the Yellow Sea, which forms in spring, thrives in summer, and fades
in autumn as thermocline declines. TF intensity ⋎ST⋎ is defined to describe the distribution of TF. Based on the MASNUM wave-tide-circulation coupled model, temperature distribution
in the Yellow Sea was simulated with and without tidal effects. Along 36°N, distribution of TF from the simulated results
are compared with the observations, and a quantitative analysis is introduced to evaluate the tidal effects on the forming
and maintaining processes of the TF. Tidal mixing and the circulation structure adapting to it are the main causes of the
TF.
Supported by the National Basic Research Program of China (No. G1999043809) and the National Science Foundation of China (No.
49736190). 相似文献
In this paper, two factors — the redistribution of the density and the variation in the angular velocity of the Earth rotation, that affect the adopted value of the flattening for equidensity surface within the Earth, are discussed. The computational results show that the contribution of the redistribution of the density in the Earth interior (especially in the core) on the change of the flattening at the core-mantle boundary (CMB) is marginal, and that the calculated value of the flattening at the CMB can be in good agreement with the VLBI observed value so long as the fact that the angular velocity of the Earth rotation has undergone the tidal evolution is taken into account. As a result, this paper presents a set of recommended values of the dynamical parameters of the Earth (see Table III) for computing Earth's forced nutation series. 相似文献